Palabras clave
Ultrasonido
Polipropileno
Conductividad térmica
Química
Polipropileno
Conductividad térmica
Química
Cómo citar
Martínez-Colunga, J., Cruz-Delgado, V., Sánchez-Valdés, S., Mata-Padilla, J., & Benavides-Cantú, R. (2025). Desarrollo de compuestos de PP/MWCNT mediante la aplicación de ultrasonido de frecuencia fija. Revista Latinoamericana De Difusión Científica, 7(13), 79-99. https://doi.org/10.5281/zenodo.15832367
Resumen
Se estudió el efecto de un mezclador estático ultrasónico de frecuencia fija de 20kHz en la obtención de compuestos de polipropileno y nanotubos de carbono de pared múltiple (MWCNT). El ultrasonido fue aplicado en estado fundido del compuesto mediante un mezclador estático ultrasónico, colocado a la salida de un extrusor monotornillo. Los compuestos de PP/MWCNTs obtenidos se caracterizaron por DSC, TGA, SEM, RAMAN y se determinaron sus propiedades de conductividad térmica y eléctrica, así como sus propiedades de tensión. Se observó un aumento en la cristalinidad del PP en los compuestos producto del efecto nucleante de los nanotubos de carbono. Los compuestos de PP/MWCNTs con tratamiento ultrasónico presentaron una mejor dispersión de los MWCNTs, lo cual contribuyo al incremento del módulo de elasticidad, una mejor estabilidad térmica y a un incrementó en la conductividad térmica y un aumento significativo en la conductividad eléctrica.
Citas
Ávila-Orta C. A., González-Morones P., Agüero-Valdez D., González-Sánchez A., Martínez-Colunga J.G., Mata-PadillaJ.M., Cruz-Delgado V.J. (2018). Ultrasound-Assisted Melt Extrusion of Polymer Nanocomposites,Intechopen, Chapter of book Nanocomposites 2018 Edited by Subbarayan Sivasankaran, doi:10.5772/intechopen.80216
Brian P. Grady, Francisco Pompeo, Robert L. Shambaugh, and Daniel E. Resasco (2002). The Journal of Physical Chemistry B 2002 106 (23), 5852-5858. DOI: 10.1021/jp014622y
Chena L, Pang X.J., Yu Z.L. (2007). Study on polycarbonate/multi-walled carbon nanotubes composite produced by melt processing, Materials Science and Engineering A 457 (2007) 287–291. https://doi.org/10.1016/j.msea.2007.01.107
García-López, E. I., Aoun, N., & Marcì, G. (2024). An Overview of the Sustainable Depolymerization/Degradation of Polypropylene Microplastics by Advanced Oxidation Technologies. Molecules, 29(12), 2816. https://doi.org/10.3390/molecules29122816
Gaurav R. Kasaliwal, Sven Pegel, Andreas Göldel, Petra Pötschke, Gert Heinrich (2010). Analysis of agglomerate dispersion mechanisms of multiwalled carbon nanotubes during melt mixing in polycarbonate, Polymer 51 (2010) 2708-2720. https://doi.org/10.1016/j.polymer.2010.02.048
Grady B.P., Pompeo F., Shambaugh R.L., Resasco D.E. (2002). Nucleation of Polypropylene Crystallization by Single-Walled Carbon Nanotubes, J. Phys. Chem. B 2002, 106, 5852-5858
Guo W.Y., Peng B. (2007) Ultrasonic Degradation Studies and Its Effect on Thermal Properties of Polypropylene. Polym Plast Techn Eng 46(9): 879-884. https://doi.org/10.1080/03602550701280224
Hemmati M., Shariatpanahi H., Ghorbanzadeh Ahangari M., Fereidoon A., Narimani A. (2012). Effect of Polypropylene–Grafted–Maleic Anhydride Compatibilizer on the Physical Properties of Polypropylene/Carbon Nanotube Composites, Polymers & Polymer Composites, 2012, 20(6) pp 559-566. https://doi.org/10.1177/096739111202000606
Lecocq H., Garois N., Lhost O., Girard P. F., Cassagnau P, A.Serghei (2020). Polypropylene/carbon nanotubes composite materials with enhanced electromagnetic interference shielding performance: Properties and modeling, Composites Part B: Engineering Volume 189, 15 May 2020, 107866, https://doi.org/10.1016/j.compositesb.2020.107866
Li X, Jia W., Dong B., Yuan H., Su F., Wang Z., Wang Y., Liu C., Shen C., Shao C. (2019). Structure and Mechanical Properties of Multi-Walled Carbon Nanotubes-Filled Isotactic Polypropylene Composites Treated by Pressurization at Different Rates, Polymers 2019, 11, 1294. doi:10.3390/polym11081294
Marco C., Naffakh M., Gomez M.A., Santoro G., Ellis G. (2011). The Crystallization of Polypropylene in Multiwall Carbon Nanotube-Based Composites POLYMER COMPOSITES—-2011,324-333. https://doi.org/10.1002/pc.21059
Martinez Colunga J.G.,Sanchez-Valdes S., Ramos de Valle L.F., Ramirez-Vargas E., Benavides Cantú R., Perez Camacho O., Avila-Orta C. A., Espinoza-Martínez A. B., Mata-Padilla J.M., Cruz Delgado V. J, Lozano T. (2021). Anhydride Grafting on Carbon Nanotubes Using Ultrasound and its Effect on Polypropylene Nanocomposite Properties, Polymer-Plastics Technology and Materials, , 2021 60(10), pp 1066-1083 | Received 08 Sep 2020, Accepted 12 Jan 2021, Published online: 21 Feb 2021 https://doi.org/10.1080/25740881.2021.1876881
Mata-Padilla J.M., Avila-Orta C.A., Medellin-Rodriguez F.J., Hernandez- Hernandez E., Jimenez-Barrera R.M., Cruz-Delgado V.J., Valdez-Garza J. A., Solis-Rosales S.G., Torres-Martinez A., Lozano-Estrada M., Diaz-Barriga Castro E. (2015). Structural and Morphological Studies on the Deformation Behavior of Polypropylene/Multi-Walled Carbon Nanotubes Nanocomposites Prepared Through Ultrasound-Assisted Melt Extrusion Process, Journal Of Polymer Science, Part B: Polymer Physics 2015, 53, 475–491. https://doi.org/10.1002/polb.23655
Pandey V., Chen H., Ma J., Maia J.M.(2021). Extension-dominated improved dispersive mixing in single-screw extrusion. Part 2: Comparative analysis with twin-screw extruder, J Appl Polym Sci. 2021;138:49765-49776. https://doi.org/10.1002/app.49765.
Pandey V., Maia J.M. (2021). Extension-dominated improved dispersive mixing in single-screw extrusion. Part 1: Computational and experimental validation, J Appl Polym Sci. 2021;138:49716-49734. https://doi.org/10.1002/app.49716.
Stanciu N.V., Stan F., Sandu I.L., Fetecau C., Turcanu A.M. (2021). Thermal, Rheological, Mechanical, and Electrical Properties of Polypropylene/Multi-Walled Carbon Nanotube Nanocomposites, Polymers 2021, 13(2), 187; https://doi.org/10.3390/polym13020187
Tabuani D., Granelli W., Camino G., Claes M. (2007). Polypropylene based carbon nanotubes composites: structure and properties, e-Polymers 2007, no. 103. doi:10.1515/epoly.2008.8.1.1178
Uwa O. Uyor, Patricia A. Popoola, Olawale M. Popoola, Aigbodion V.S (2022). A review of recent advances on the properties of polypropylene - carbon nanotubes composites Journal of Thermoplastic Composite Materials, First Published March 28, 2022 Research Article, https://doi.org/10.1177/08927057221077868
Yan X., Dong H., Xiao Z., Liu Y, Liu T., Chae H.G., Kumar S. (2017). Effect of high-shear mixing by twin-screw extruder on the dispersion and homogeneity of polyacrylonitrile/carbon nanotube composite solution, Polymer Composites, 38(4) 2017: 719-726. https://doi.org/10.1002/pc.23631
Yin X. Li S., He G., Feng Y., Wen J. (2018). Preparation and characterization of CNTs/UHMWPE nanocomposites via a novel mixer under synergy of ultrasonic wave and extensional deformation, Ultrasonics - Sonochemistry 43 (2018) 15–22 https://doi.org/10.1016/j.ultsonch.2017.12.039
Zhong J, Isayev AI, Huang KY. (2014). Influence of ultrasonic treatment in PP/CNT composites using masterbatch dilution method, Polymer, Vol.55, No.7, 1745-1755, 2014, https://doi.org/10.1016/j.polymer.2014.02.014
Zhong J., Isayev A.I., Zhang X. (2016). Ultrasonic twin screw compounding of polypropylene with carbon nanotubes, graphene nanoplates and carbon black, European Polymer Journal Volume 80, July 2016, Pages 16-39. https://doi.org/10.1016/j.eurpolymj.2016.04.028
Brian P. Grady, Francisco Pompeo, Robert L. Shambaugh, and Daniel E. Resasco (2002). The Journal of Physical Chemistry B 2002 106 (23), 5852-5858. DOI: 10.1021/jp014622y
Chena L, Pang X.J., Yu Z.L. (2007). Study on polycarbonate/multi-walled carbon nanotubes composite produced by melt processing, Materials Science and Engineering A 457 (2007) 287–291. https://doi.org/10.1016/j.msea.2007.01.107
García-López, E. I., Aoun, N., & Marcì, G. (2024). An Overview of the Sustainable Depolymerization/Degradation of Polypropylene Microplastics by Advanced Oxidation Technologies. Molecules, 29(12), 2816. https://doi.org/10.3390/molecules29122816
Gaurav R. Kasaliwal, Sven Pegel, Andreas Göldel, Petra Pötschke, Gert Heinrich (2010). Analysis of agglomerate dispersion mechanisms of multiwalled carbon nanotubes during melt mixing in polycarbonate, Polymer 51 (2010) 2708-2720. https://doi.org/10.1016/j.polymer.2010.02.048
Grady B.P., Pompeo F., Shambaugh R.L., Resasco D.E. (2002). Nucleation of Polypropylene Crystallization by Single-Walled Carbon Nanotubes, J. Phys. Chem. B 2002, 106, 5852-5858
Guo W.Y., Peng B. (2007) Ultrasonic Degradation Studies and Its Effect on Thermal Properties of Polypropylene. Polym Plast Techn Eng 46(9): 879-884. https://doi.org/10.1080/03602550701280224
Hemmati M., Shariatpanahi H., Ghorbanzadeh Ahangari M., Fereidoon A., Narimani A. (2012). Effect of Polypropylene–Grafted–Maleic Anhydride Compatibilizer on the Physical Properties of Polypropylene/Carbon Nanotube Composites, Polymers & Polymer Composites, 2012, 20(6) pp 559-566. https://doi.org/10.1177/096739111202000606
Lecocq H., Garois N., Lhost O., Girard P. F., Cassagnau P, A.Serghei (2020). Polypropylene/carbon nanotubes composite materials with enhanced electromagnetic interference shielding performance: Properties and modeling, Composites Part B: Engineering Volume 189, 15 May 2020, 107866, https://doi.org/10.1016/j.compositesb.2020.107866
Li X, Jia W., Dong B., Yuan H., Su F., Wang Z., Wang Y., Liu C., Shen C., Shao C. (2019). Structure and Mechanical Properties of Multi-Walled Carbon Nanotubes-Filled Isotactic Polypropylene Composites Treated by Pressurization at Different Rates, Polymers 2019, 11, 1294. doi:10.3390/polym11081294
Marco C., Naffakh M., Gomez M.A., Santoro G., Ellis G. (2011). The Crystallization of Polypropylene in Multiwall Carbon Nanotube-Based Composites POLYMER COMPOSITES—-2011,324-333. https://doi.org/10.1002/pc.21059
Martinez Colunga J.G.,Sanchez-Valdes S., Ramos de Valle L.F., Ramirez-Vargas E., Benavides Cantú R., Perez Camacho O., Avila-Orta C. A., Espinoza-Martínez A. B., Mata-Padilla J.M., Cruz Delgado V. J, Lozano T. (2021). Anhydride Grafting on Carbon Nanotubes Using Ultrasound and its Effect on Polypropylene Nanocomposite Properties, Polymer-Plastics Technology and Materials, , 2021 60(10), pp 1066-1083 | Received 08 Sep 2020, Accepted 12 Jan 2021, Published online: 21 Feb 2021 https://doi.org/10.1080/25740881.2021.1876881
Mata-Padilla J.M., Avila-Orta C.A., Medellin-Rodriguez F.J., Hernandez- Hernandez E., Jimenez-Barrera R.M., Cruz-Delgado V.J., Valdez-Garza J. A., Solis-Rosales S.G., Torres-Martinez A., Lozano-Estrada M., Diaz-Barriga Castro E. (2015). Structural and Morphological Studies on the Deformation Behavior of Polypropylene/Multi-Walled Carbon Nanotubes Nanocomposites Prepared Through Ultrasound-Assisted Melt Extrusion Process, Journal Of Polymer Science, Part B: Polymer Physics 2015, 53, 475–491. https://doi.org/10.1002/polb.23655
Pandey V., Chen H., Ma J., Maia J.M.(2021). Extension-dominated improved dispersive mixing in single-screw extrusion. Part 2: Comparative analysis with twin-screw extruder, J Appl Polym Sci. 2021;138:49765-49776. https://doi.org/10.1002/app.49765.
Pandey V., Maia J.M. (2021). Extension-dominated improved dispersive mixing in single-screw extrusion. Part 1: Computational and experimental validation, J Appl Polym Sci. 2021;138:49716-49734. https://doi.org/10.1002/app.49716.
Stanciu N.V., Stan F., Sandu I.L., Fetecau C., Turcanu A.M. (2021). Thermal, Rheological, Mechanical, and Electrical Properties of Polypropylene/Multi-Walled Carbon Nanotube Nanocomposites, Polymers 2021, 13(2), 187; https://doi.org/10.3390/polym13020187
Tabuani D., Granelli W., Camino G., Claes M. (2007). Polypropylene based carbon nanotubes composites: structure and properties, e-Polymers 2007, no. 103. doi:10.1515/epoly.2008.8.1.1178
Uwa O. Uyor, Patricia A. Popoola, Olawale M. Popoola, Aigbodion V.S (2022). A review of recent advances on the properties of polypropylene - carbon nanotubes composites Journal of Thermoplastic Composite Materials, First Published March 28, 2022 Research Article, https://doi.org/10.1177/08927057221077868
Yan X., Dong H., Xiao Z., Liu Y, Liu T., Chae H.G., Kumar S. (2017). Effect of high-shear mixing by twin-screw extruder on the dispersion and homogeneity of polyacrylonitrile/carbon nanotube composite solution, Polymer Composites, 38(4) 2017: 719-726. https://doi.org/10.1002/pc.23631
Yin X. Li S., He G., Feng Y., Wen J. (2018). Preparation and characterization of CNTs/UHMWPE nanocomposites via a novel mixer under synergy of ultrasonic wave and extensional deformation, Ultrasonics - Sonochemistry 43 (2018) 15–22 https://doi.org/10.1016/j.ultsonch.2017.12.039
Zhong J, Isayev AI, Huang KY. (2014). Influence of ultrasonic treatment in PP/CNT composites using masterbatch dilution method, Polymer, Vol.55, No.7, 1745-1755, 2014, https://doi.org/10.1016/j.polymer.2014.02.014
Zhong J., Isayev A.I., Zhang X. (2016). Ultrasonic twin screw compounding of polypropylene with carbon nanotubes, graphene nanoplates and carbon black, European Polymer Journal Volume 80, July 2016, Pages 16-39. https://doi.org/10.1016/j.eurpolymj.2016.04.028
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